With 19-Across, item for many cobblers

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Possible Answers: PIE.

Random information on the term “PIE”:
Alternative notations: The aspirated stops are sometimes written as *bh, *dh, *ǵh, *gh, *gʷh; for the palatals, *k̑, *g̑ are often used; and *i̯, *u̯ can replace *y, *w.
Taken from Wikipedia