Now we are looking on the crossword clue: Certain libation.
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Possible Answers: ALE.
Random information on the term “ALE”:
Ale is a type of beer brewed from malted barley using a warm fermentation with a strain of brewers’ yeast. The yeast will ferment the beer quickly, giving it a sweet, full bodied and fruity taste. Most ales contain hops, which help preserve the beer and impart a bitter herbal flavour that balances the sweetness of the malt.
Taken from Wikipedia